OPTICAL PROPERTIES OF TRANSITION METAL IONS IN OXIDE GLASS APPLIED IN LIGHTING
Main Article Content
Abstract
B2O3 - TeO2 - ZnO- Na2O glasses doped with 0% to 5% mol of Mn2+ were prepared using the melt quenching method. Measurements of X-ray diffraction confirmed the non-crystalline structure of samples. Optical properties were analyzed by excitation and emission spectra. The emission spectra showed an intense emission in the 610 nm (red region), a corresponding transition of 4T1(G)→6A1 (G). From the results of emission spectra, we determined the color coordinates of all samples excited by 410nm wavelength. The results indicated that B2O3- TeO2 - ZnO-Na2O glasses doped Mn2+ ions can provide a new platform to design and fabricate novel luminescent materials for color LED, photonic devices, and display applications.
Keywords
doped ion Mn2 and lighting, optical properties, oxide glass
Article Details
References
Adachi, S. (2022). Photoluminescence spectroscopy of Mn2+ in zero-thermal expansion Zn4B6O13 green-emitting phosphor. Journal of Luminescence, 246, Article 118814. https://doi.org/10.1016/j.jlumin.2022.118814
Ami Hazlin, M. N., Halimah, M. K., & Muhammad, F. D. (2018). Absorption and emission analysis of zinc borotellurite glass doped with dysprosium oxide nanoparticles for generation of white light. Journal of Luminescence, 196, 498-503. https://doi.org/10.1016/j.jlumin.2017.11.054
An, J. M., Li, D. S., He, X. Y., Pun, E. Y. B., & Lin, H. (2021). Revealing the multicolor mechanism in borotellurite glass phosphor: From individual emission of dual-modes to WLED applications. Journal of Luminescence, 234, Article 117972. https://doi.org/10.1016/j.jlumin.2021.117972
Bashar, Kh. A., Lakshminarayana, G., Baki, S. O., Mohammed, A.-B. F. A., Caldiño, U., Meza-Rocha, A. N., Singh, V., Kityk, I. V., & Mahdi, M. A. (2019). Tunable white-light emission from Pr3+/Dy3+ co-doped B2O3—TeO2 PbO - ZnO Li2O - Na2O glasses. Optical Materials, 88, 558-569. https://doi.org/10.1016/j.optmat.2018.12.028
Batista, E. A., Silva, A. C. A., de Lima, T. K., Guimarães, E. V., da Silva, R. S., & Dantas, N. O. (2021). Effect of the location of Mn2+ ions in the optical and magnetic properties of ZnO nanocrystals. Journal of Alloys and Compounds, 850, Article 156611. https://doi.org/10.1016/j.jallcom.2020.156611
Batygov, S. Kh., Brekhovskikh, M. N., Moiseeva, L. V., Makhov, V. N., Kirikova, N. Yu., Shukshin, V. E., & Fedorov, V. A. (2019). Optical Properties of Manganese-Activated Fluorozirconate Glasses. Inorganic Materials, 55(11), 1185-1188. https://doi.org/10.1134/S0020168519110025
Brekhovskikh, M., Batygov, S., Moiseeva, L., Solodovnikov, S., Zhidkova, I., Denisov, G., & dvsd, scasdv. (2018). Optical Properties and Electron Paramagnetic Resonance of MnO2-Doped Fluorozirconate Glasses. Inorganic Materials, 54, 1157-1161. https://doi.org/10.1134/S0020168518110031
Deopa, N., Rao, A. S., Choudhary, A., Saini, S., Navhal, A., Jayasimhadri, M., Haranath, D., & Vijaya Prakash, G. (2018). Photoluminescence investigations on Sm3+ ions doped borate glasses for tricolor w-LEDs and lasers. Materials Research Bulletin, 100, 206-212. https://doi.org/10.1016/j.materresbull.2017.12.019
Dexter, D. L. (1953). A Theory of Sensitized Luminescence in Solids. The Journal of Chemical Physics, 21(5), 836-850. https://doi.org/10.1063/1.1699044
Doddoji, R., Tuyen, H. V., Hong, T. T., Thanh Son, L. V., Khan, D. T., Dat, T. N., Lien, P., & Dung, P. T. (2023). Visible DC approach by controlling the UV light in (Eu3+/Tb3+) co-activated TBZN glasses for w-LEDs and a-Si solar cells. Ceramics International, 49(10), 16341-16351. https://doi.org/10.1016/j.ceramint.2023.01.236
Dong, Q., Yang, F., Cui, J., Tian, Y., Liu, S., Du, F., Peng, J., & Ye, X. (2019). Enhanced narrow green emission and thermal stability in γ-AlON: Mn2+, Mg2+ phosphor via charge compensation. Ceramics International, 45(9), 11868-11875. https://doi.org/10.1016/j.ceramint.2019.03.069
Elkhoshkhany, N., Abbas, R., El-Mallawany, R., & Hathot, S. F. (2017). Optical properties and crystallization of bismuth boro-tellurite glasses. Journal of Non-Crystalline Solids, 476,
15-24. https://doi.org/10.1016/j.jnoncrysol.2017.06.031
Förster, Th. (1948). Zwischenmolekulare Energiewanderung und Fluoreszenz. Annalen der Physik, 437(1-2), 55-75. https://doi.org/10.1002/andp.19484370105
Hu, T., Lin, H., Xu, J., Wang, B., Wang, J., & Wang, Y. (2017). Color-tunable persistent luminescence in oxyfluoride glass and glass ceramic containing Mn2+:α-Zn2SiO4 nanocrystals. Journal of Materials Chemistry C, 5(6), 1479-1487. https://doi.org/10.1039/C6TC05340H
Inokuti, M., & Hirayama, F. (1965). Influence of Energy Transfer by the Exchange Mechanism on Donor Luminescence. The Journal of Chemical Physics, 43(6), 1978-1989. https://doi.org/10.1063/1.1697063
Luo, H., Cao, J., Li, X., Wang, X., & Peng, M. (2018). Topological tailoring of structure and defects to enhance red to near-infrared afterglow from Mn2+-doped germanate photonic glasses. Journal of Materials Chemistry C, 6(43), 11525-11535. https://doi.org/10.1039/C8TC03477J
Mukamil, S., Shahid, N., Sarumaha, C., Khattak, S. A., Wabaidur, S. M., Islam, M. A., Kothan, S., Shoaib, M., Khan, I., Ullah, I., Kaewkhao, J., & Rooh, G. (2022). Spectroscopic investigation of dysprosium doped bismuth-borate glasses for white light application. Optical Materials, 127, Article 112291. https://doi.org/10.1016/j.optmat.2022.112291
Ni, Q., Li, M., Zhu, Q., Huo, J., & Wang, Q. (2021). Composition adjustment verifies structure-property correlation in narrow-band green-emitting Zn4-xMgxB6O13: Mn2+ phosphor. Journal of Luminescence, 236, Article 118101. https://doi.org/10.1016/j.jlumin.2021.118101
Ravi Kumar, G., Uday Baskar, S., & Rao, M. C. (2018). Role of Mn2+ ions on optical and luminescent properties of CaF2–Y2O3–ZnO–B2O3–SiO2 glasses. Results in Physics, 10, 546-557. https://doi.org/10.1016/j.rinp.2018.05.046
Sumalatha, C., Doddoji, R., Venkateswarlu, M., Rani, P. R., Swapna, K., Mahamuda, Sk., & Rao, A. S. (2020). White light emission from Dy3+-doped ZnO + Bi2O3 + BaF2 + B2O3 + TeO2 glasses: Structural and spectroscopic properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 240, Article 118568. https://doi.org/10.1016/j.saa.2020.118568
Tran, T. H., Pham, Y., Vu, X. Q., & Phan, T. D. (2015). Luminescence Properties of Ce/Tb/Sm Co-Doped Tellurite Glass for White Leds Application. Materials Transactions, 56(9), 1419-1421. https://doi.org/10.2320/matertrans.MA201509
Tran, T. H., Phan, T. D., & Vu, X. Q. (2019). Luminescence studies of Eu3+ ions in tellurite glass ceramics. International Journal of Modern Physics B, 33, Article 1950179. https://doi.org/10.1142/S0217979219501790
Van Tuyen, H., Hong, T. T., Van Thanh Son, L., Lien, N. T. Q., Doddoji, R., Nguyen, H. B., & Son, L. V. T. (2023). Effects of Ce3+/Sm3+ co-doping as a luminescent modifier in borotellurite glasses for solid-state lighting. Journal of Materials Science: Materials in Electronics, 34(10), Article 896. https://doi.org/10.1007/s10854-023-10265-5
Wei, Y., Han, X., Song, E., & Zhang, Q. (2019). Photoluminescence and phosphorescence of Mn2+ ion activated green phosphor Na2ZnSiO4:Mn2+ synthesized by self-reduction. Materials Research Bulletin, 113, 90-96. https://doi.org/10.1016/j.materresbull.2019.01.022
Zhang, X., Zhu, Z., Guo, Z., Sun, Z., Yang, Z., Zhang, T., Zhang, J., Wu, Z., & Wang, Z. (2019). Dopant preferential site occupation and high efficiency white emission in K2BaCa(PO4)2:Eu2+,Mn2+ phosphors for high quality white LED applications. Inorganic Chemistry Frontiers, 6(5), 1289-1298. https://doi.org/10.1039/C9QI00138G
Zhu, Y., Liang, Y., Liu, S., Li, H., & Chen, J. (2019). Narrow-Band Green-Emitting Sr2MgAl22O36:Mn2+ Phosphors with Superior Thermal Stability and Wide Color Gamut for Backlighting Display Applications. Advanced Optical Materials, 7(6), Article 1801419. https://doi.org/10.1002/adom.201801419
Ami Hazlin, M. N., Halimah, M. K., & Muhammad, F. D. (2018). Absorption and emission analysis of zinc borotellurite glass doped with dysprosium oxide nanoparticles for generation of white light. Journal of Luminescence, 196, 498-503. https://doi.org/10.1016/j.jlumin.2017.11.054
An, J. M., Li, D. S., He, X. Y., Pun, E. Y. B., & Lin, H. (2021). Revealing the multicolor mechanism in borotellurite glass phosphor: From individual emission of dual-modes to WLED applications. Journal of Luminescence, 234, Article 117972. https://doi.org/10.1016/j.jlumin.2021.117972
Bashar, Kh. A., Lakshminarayana, G., Baki, S. O., Mohammed, A.-B. F. A., Caldiño, U., Meza-Rocha, A. N., Singh, V., Kityk, I. V., & Mahdi, M. A. (2019). Tunable white-light emission from Pr3+/Dy3+ co-doped B2O3—TeO2 PbO - ZnO Li2O - Na2O glasses. Optical Materials, 88, 558-569. https://doi.org/10.1016/j.optmat.2018.12.028
Batista, E. A., Silva, A. C. A., de Lima, T. K., Guimarães, E. V., da Silva, R. S., & Dantas, N. O. (2021). Effect of the location of Mn2+ ions in the optical and magnetic properties of ZnO nanocrystals. Journal of Alloys and Compounds, 850, Article 156611. https://doi.org/10.1016/j.jallcom.2020.156611
Batygov, S. Kh., Brekhovskikh, M. N., Moiseeva, L. V., Makhov, V. N., Kirikova, N. Yu., Shukshin, V. E., & Fedorov, V. A. (2019). Optical Properties of Manganese-Activated Fluorozirconate Glasses. Inorganic Materials, 55(11), 1185-1188. https://doi.org/10.1134/S0020168519110025
Brekhovskikh, M., Batygov, S., Moiseeva, L., Solodovnikov, S., Zhidkova, I., Denisov, G., & dvsd, scasdv. (2018). Optical Properties and Electron Paramagnetic Resonance of MnO2-Doped Fluorozirconate Glasses. Inorganic Materials, 54, 1157-1161. https://doi.org/10.1134/S0020168518110031
Deopa, N., Rao, A. S., Choudhary, A., Saini, S., Navhal, A., Jayasimhadri, M., Haranath, D., & Vijaya Prakash, G. (2018). Photoluminescence investigations on Sm3+ ions doped borate glasses for tricolor w-LEDs and lasers. Materials Research Bulletin, 100, 206-212. https://doi.org/10.1016/j.materresbull.2017.12.019
Dexter, D. L. (1953). A Theory of Sensitized Luminescence in Solids. The Journal of Chemical Physics, 21(5), 836-850. https://doi.org/10.1063/1.1699044
Doddoji, R., Tuyen, H. V., Hong, T. T., Thanh Son, L. V., Khan, D. T., Dat, T. N., Lien, P., & Dung, P. T. (2023). Visible DC approach by controlling the UV light in (Eu3+/Tb3+) co-activated TBZN glasses for w-LEDs and a-Si solar cells. Ceramics International, 49(10), 16341-16351. https://doi.org/10.1016/j.ceramint.2023.01.236
Dong, Q., Yang, F., Cui, J., Tian, Y., Liu, S., Du, F., Peng, J., & Ye, X. (2019). Enhanced narrow green emission and thermal stability in γ-AlON: Mn2+, Mg2+ phosphor via charge compensation. Ceramics International, 45(9), 11868-11875. https://doi.org/10.1016/j.ceramint.2019.03.069
Elkhoshkhany, N., Abbas, R., El-Mallawany, R., & Hathot, S. F. (2017). Optical properties and crystallization of bismuth boro-tellurite glasses. Journal of Non-Crystalline Solids, 476,
15-24. https://doi.org/10.1016/j.jnoncrysol.2017.06.031
Förster, Th. (1948). Zwischenmolekulare Energiewanderung und Fluoreszenz. Annalen der Physik, 437(1-2), 55-75. https://doi.org/10.1002/andp.19484370105
Hu, T., Lin, H., Xu, J., Wang, B., Wang, J., & Wang, Y. (2017). Color-tunable persistent luminescence in oxyfluoride glass and glass ceramic containing Mn2+:α-Zn2SiO4 nanocrystals. Journal of Materials Chemistry C, 5(6), 1479-1487. https://doi.org/10.1039/C6TC05340H
Inokuti, M., & Hirayama, F. (1965). Influence of Energy Transfer by the Exchange Mechanism on Donor Luminescence. The Journal of Chemical Physics, 43(6), 1978-1989. https://doi.org/10.1063/1.1697063
Luo, H., Cao, J., Li, X., Wang, X., & Peng, M. (2018). Topological tailoring of structure and defects to enhance red to near-infrared afterglow from Mn2+-doped germanate photonic glasses. Journal of Materials Chemistry C, 6(43), 11525-11535. https://doi.org/10.1039/C8TC03477J
Mukamil, S., Shahid, N., Sarumaha, C., Khattak, S. A., Wabaidur, S. M., Islam, M. A., Kothan, S., Shoaib, M., Khan, I., Ullah, I., Kaewkhao, J., & Rooh, G. (2022). Spectroscopic investigation of dysprosium doped bismuth-borate glasses for white light application. Optical Materials, 127, Article 112291. https://doi.org/10.1016/j.optmat.2022.112291
Ni, Q., Li, M., Zhu, Q., Huo, J., & Wang, Q. (2021). Composition adjustment verifies structure-property correlation in narrow-band green-emitting Zn4-xMgxB6O13: Mn2+ phosphor. Journal of Luminescence, 236, Article 118101. https://doi.org/10.1016/j.jlumin.2021.118101
Ravi Kumar, G., Uday Baskar, S., & Rao, M. C. (2018). Role of Mn2+ ions on optical and luminescent properties of CaF2–Y2O3–ZnO–B2O3–SiO2 glasses. Results in Physics, 10, 546-557. https://doi.org/10.1016/j.rinp.2018.05.046
Sumalatha, C., Doddoji, R., Venkateswarlu, M., Rani, P. R., Swapna, K., Mahamuda, Sk., & Rao, A. S. (2020). White light emission from Dy3+-doped ZnO + Bi2O3 + BaF2 + B2O3 + TeO2 glasses: Structural and spectroscopic properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 240, Article 118568. https://doi.org/10.1016/j.saa.2020.118568
Tran, T. H., Pham, Y., Vu, X. Q., & Phan, T. D. (2015). Luminescence Properties of Ce/Tb/Sm Co-Doped Tellurite Glass for White Leds Application. Materials Transactions, 56(9), 1419-1421. https://doi.org/10.2320/matertrans.MA201509
Tran, T. H., Phan, T. D., & Vu, X. Q. (2019). Luminescence studies of Eu3+ ions in tellurite glass ceramics. International Journal of Modern Physics B, 33, Article 1950179. https://doi.org/10.1142/S0217979219501790
Van Tuyen, H., Hong, T. T., Van Thanh Son, L., Lien, N. T. Q., Doddoji, R., Nguyen, H. B., & Son, L. V. T. (2023). Effects of Ce3+/Sm3+ co-doping as a luminescent modifier in borotellurite glasses for solid-state lighting. Journal of Materials Science: Materials in Electronics, 34(10), Article 896. https://doi.org/10.1007/s10854-023-10265-5
Wei, Y., Han, X., Song, E., & Zhang, Q. (2019). Photoluminescence and phosphorescence of Mn2+ ion activated green phosphor Na2ZnSiO4:Mn2+ synthesized by self-reduction. Materials Research Bulletin, 113, 90-96. https://doi.org/10.1016/j.materresbull.2019.01.022
Zhang, X., Zhu, Z., Guo, Z., Sun, Z., Yang, Z., Zhang, T., Zhang, J., Wu, Z., & Wang, Z. (2019). Dopant preferential site occupation and high efficiency white emission in K2BaCa(PO4)2:Eu2+,Mn2+ phosphors for high quality white LED applications. Inorganic Chemistry Frontiers, 6(5), 1289-1298. https://doi.org/10.1039/C9QI00138G
Zhu, Y., Liang, Y., Liu, S., Li, H., & Chen, J. (2019). Narrow-Band Green-Emitting Sr2MgAl22O36:Mn2+ Phosphors with Superior Thermal Stability and Wide Color Gamut for Backlighting Display Applications. Advanced Optical Materials, 7(6), Article 1801419. https://doi.org/10.1002/adom.201801419