DEVELOPMENT OF AN ARTIFICIAL NEURAL NETWORK MODEL FOR RAPID DETERMINATION OF NAOH SOLUTION CONCENTRATION USING THE TRANSMISSION SPECTRUM OF LOW-ENERGY GAMMA RAYS AT 59.54 KEV

Nguyen Thanh Dat1, , Tran Vu Thien An1, Vo Diep Trung Tin1, Tran Trung Nguyen1, Huynh Dinh Chuong2, Hoang Thi Kieu Trang2, Hoang Duc Tam1
1 Ho Chi Minh City University of Education, Vietnam
2 University of Science, Vietnam National University Ho Chi Minh City, Vietnam

Main Article Content

Abstract

This study proposes a new approach for rapidly determining the concentration of NaOH solutions by measuring the attenuation of a low-energy 59.54 keV γ-ray beam emitted from a 241Am source and using an artificial neural network (ANN) trained directly on raw spectra. First, Monte Carlo simulations configured are used to generate spectral data. Then these spectral data are directly extracted to train and optimize an ANN model. The predictive performance of the optimized network is benchmarked against a conventional calibration curve that relates the transmission ratio (ln R) between water and NaOH solutions to their concentrations. The obtained results show that the ANN model achieves an average deviation of less than 2.8% from reference concentrations across the tested range, whereas the calibration curve yields deviations above 6.0%. In the low-concentration region (C = 5.0%), the ANN achieves a 2.5% deviation, markedly better than the approximately 12.6% deviation of the calibration curve. The findings suggest that integrating low-energy γ-ray transmission measurements with an ANN model offers a promising methodology for high-precision monitoring of alkaline solutions.

Article Details

References

Dai, F., Zhuang, Q., Huang, G., Deng, H., & Zhang, X. (2023). Infrared spectrum characteristics and quantification of OH groups in coal. ACS omega, 8(19), 17064-17076. https://doi.org/10.1021/acsomega.3c01336
Dorn, M., Kareth, S., Weidner, E., & Petermann, M. (2024). Electrical conductivity of lithium, sodium, potassium, and quaternary ammonium salts in water, acetonitrile, methanol, and ethanol over a wide concentration range. J. Chem. Eng. Data., 69(4), 1493-1502. https://doi.org/10.1021/acs.jced.3c00691
Goorley, T., James, M., Booth, T., Brown, F., Bull, J., Cox, L. J., Durkee, J., Elson, J., Fensin, M., Forster, R. A., Hendricks, J., Hughes, H. G., Johns, R., Kiedrowski, B., Martz, R., Mashnik, S., McKinney, G., Pelowitz, D., Prael, R., ... Werbein, S. (2012). Initial MCNP6 release overview. Nuclear Technology, 180(3), 298–315. https://doi.org/10.13182/NT11-135
Huynh, D. C., Nguyen, Q. H., Nguyen, T. M. L., Vo, H. N., & Tran, T. T. (2019). Validation of gamma scanning method for optimizing NaI(Tl) detector model in Monte Carlo simulation. Applied Radiation and Isotopes, 149, 1–8. https://doi.org/10.1016/j.apradiso.2019.04.009
Huynh, C. D., Truong, S. T., Le, T. N. T., Nguyen, L. T. T., & Hoang, T. D. (2021). The first result in the determination of the percentage concentration of sulfuric acid solution based on the gamma transmission technique with an energy of 662 ke. STDJ-NS, 5(2), 1179-1188. https://doi.org/10.32508/stdjns.v5i2.1010
Nguyen, T. D., Hoang, T. K. T., & Hoang, D. T. (2024). Determining the concentration of base solution based on gamma transition technique combined with Monte Carlo simulation and artificial neutral network: preliminary results. HCMUE Journal of Science, 21(1), 162. https://doi.org/10.54607/hcmue.js.21.1.3925(2024)
Perry, R.H., Green, D.W., Maloney, J. O., 1997. CHEMICAL ENGINEERS ’ HANDBOOK SEVENTH Late Editor, Society.
Rhoades, J. D. (1993). Electrical conductivity methods for measuring and mapping soil salinity. Adv. Agron., 49, 201-251. https://doi.org/10.1016/S0065-2113(08)60795-6
Schmidhuber, J. (2015). Deep learning in neural networks: An overview. Neural networks, 61, 85-117. https://doi.org/10.1016/j.neunet.2014.09.003
Sue, K., & Arai, K. (2004). Specific behavior of acid–base and neutralization reactions in supercritical water. J. Supercrit. Fluids, 28(1), 57-68. https://doi.org/10.1016/S0896-8446(03)00010-X
Tong, A., Tang, X., Liu, H., Gao, H., Kou, X., & Zhang, Q. (2023). Differentiation of NaCl, NaOH, and β-Phenylethylamine using ultraviolet spectroscopy and improved adaptive artificial bee colony combined with BP-ANN algorithm. ACS Omega, 8(13), 12418–12429. https://doi.org/10.1021/acsomega.3c00271
Truong, T. S., Dang, H. A., Huynh, D. C., Nguyen, T. H., Lam, D. N., Nguyen, T. K. A., Tran, T. M. D., & Hoang, D. T. (2021). ANN coupled with Monte Carlo simulation for predicting the concentration of acids. Applied Radiation and Isotopes, 169, 109563. https://doi.org/10.1016/j.apradiso.2020.109563