EFFECT OF X-RAY IRRADIATION ON THE PHYSICAL PROPERTIES OF POLYVINYL CHLORIDE

Văn Ngọc Hoàng 1, , An Sơn Nguyễn , Viết Huy Lê , Thị Minh Sang Nguyễn , Thị Thanh Trân Lê , Thị Lệ Đỗ , Thị Phúc Nguyễn
1 Trường Đại học Đà Lạt

Main Article Content

Abstract

In this investigation, the MBR-1618R-BE (Hitachi, Japan) machine is used to generate X-rays. Low energy X-rays vary with energies 0.5 kGy, 1.0 kGy, 5 kGy, and 10 kGy radiation level, and time is 7.83 minutes, 15.75 minutes, 78.73 minutes, and 157.46 minutes respectively. This research investigates the effect of X-ray irradiation doses on the physico-chemical properties of PVC. PVC samples before and after irradiation are transferred in liquid form by using microwave digestion Mars 6 and then X-ray Powder Diffraction (XRD) to determine the structural morphological characteristics of PVC samples. XRD results show that the change of PVC polymer structure depends significantly on a radiation dose. At the diffraction peaks of angles 17.670 and 26.170, the count at the peak region decreases sharply at a low projection dose at 0.5 kGy and 1 kGy, and in this region, the structural change according to the projection dose takes the form of a linear superlative function. With higher energy from 1 kGy to 10 kGy, the effect on the PVC structure changes gradually. The study results show that the application of radiation in PVC destruction can be applied to reduce the decomposition time. It also results in less waste disposal to the environment.

 

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Author Biography

Văn Ngọc Hoàng, Trường Đại học Đà Lạt

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References

Altenhofen da Silva, M., Adeodato Vieira, M. G., Gomes Maçumoto, A. C., & Beppu, M. M. (2011). Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid. Polymer Testing, 30(5), 478-484. https://doi.org/10.1016/j.polymertesting.2011.03.008
Baumann, E., Ann (1872). Ueber einige Vinylverbindungen. In: Ann. Chem. Pharm. 163(3),
308-322
Brown, K. A., Holland, Boyd, M. R., Thresh, S., Jones, H., & Ogilvie, S. M. (2000). Economic Evaluation of PVC Waste Management. AEA Technology
Brunner, A. J. (1972). X-ray diffraction pattern of poly(vinyl chloride). Journal of Polymer Science Part B: Polymer Letters, 10(5), 379-383. https://doi.org/10.1002/pol.1972.110100509
Dang, W., Liu, J., Huang, X., Liang, J., Wang, C., Miao, P., An, Y., & Wang, X. (2018). Effects of γ-ray irradiation on the radial structure heterogeneity in Polyacrylonitrile fibers during thermal stabilization. Polymers, 10(9), 943. https://doi.org/10.3390/polym10090943
Manual for user “Operation manual X-rays irradiation system MBR-1618R-BE”
Polvi, J., & Nordlund, K. (2013). Irradiation effects in high-density polyethylene. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 312, 54-59. https://doi.org/10.1016/j.nimb.2013.07.002
Waly, S., Shehata, M., & Mahmoud, H. (2018). Effect of gamma irradiation on the physical and chemical properties of copper-poly vinyl Pyrolidone composite films. Arab Journal of Nuclear Sciences and Applications, 51(4), 1-10. https://doi.org/10.21608/ajnsa.2018.13517
Younes, M., Abdel-Rahman H. A., & Hamed, E. (2019). Effect of Gamma-Irradiation on Properties of Polymer/Fibrous/Nanomaterials Particleboard Composites, J.Chem. Soc. Pak. 41(6), 966-974.